STUDY OF THE CYCLOADDITION REACTION OF CONJUGATED OXIMES WITH AND WITHOUT LEWIS-ACID CATALYST - DEHYDROGENATION OF THE CYCLOADDUCTS TO ISOXAZOLES

Citation
Rs. Kusurkar et al., STUDY OF THE CYCLOADDITION REACTION OF CONJUGATED OXIMES WITH AND WITHOUT LEWIS-ACID CATALYST - DEHYDROGENATION OF THE CYCLOADDUCTS TO ISOXAZOLES, Journal of chemical research. Synopses, (11), 1996, pp. 478-479
Citations number
9
Categorie Soggetti
Chemistry
ISSN journal
03082342
Issue
11
Year of publication
1996
Pages
478 - 479
Database
ISI
SICI code
0308-2342(1996):11<478:SOTCRO>2.0.ZU;2-K
Abstract
Substituted isoxazoles are synthesized by dehydrogenation of the appro priate substituted isoxazolidines, prepared by 1,3-dipolar cycloadditi on of thiophene-2-carbaldehyde oxime with conventional dipolarophiles; based on these studies, cycloadducts obtained from 2-furaldehyde oxim e, previously reported as [4+2] adducts, are revised to 1,3-dipolar st ructures.