NUCLEOPHILIC-SUBSTITUTION IN BENZYLIC PHOSPHONAMIDOTHIOIC CHLORIDES -INFLUENCE OF SUBSTITUENTS ON THE ELIMINATION-ADDITION PATHWAY

Authors
HARGER MJP HURMAN BT
Citation
Mjp. Harger et Bt. Hurman, NUCLEOPHILIC-SUBSTITUTION IN BENZYLIC PHOSPHONAMIDOTHIOIC CHLORIDES -INFLUENCE OF SUBSTITUENTS ON THE ELIMINATION-ADDITION PATHWAY, Journal of chemical research. Synopses, (11), 1996, pp. 490-491
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
11
Year of publication
1996
Pages
490 - 491
Database
ISI
SICI code
0308-2342(1996):11<490:NIBPC->2.0.ZU;2-3
Abstract
The elimination-addition pathway that competes with S(N)2(P) in the re action of ArCH2P(S)(NMe(2))Cl with Et(2)NH is very sensitive to the ac idity of the benzylic C-H bond (rho 3.45).