NOVEL-APPROACH TO THE ANALYSIS OF BROAD-BAND DIELECTRIC SPECTRA

Citation
H. Schafer et al., NOVEL-APPROACH TO THE ANALYSIS OF BROAD-BAND DIELECTRIC SPECTRA, Physical review letters, 76(12), 1996, pp. 2177-2180
Citations number
20
Categorie Soggetti
Physics
Journal title
ISSN journal
00319007
Volume
76
Issue
12
Year of publication
1996
Pages
2177 - 2180
Database
ISI
SICI code
0031-9007(1996)76:12<2177:NTTAOB>2.0.ZU;2-6
Abstract
Broadband dielectric spectra are usually fitted to a superposition of contributions from one or several parametrized processes (Debye, Havri liak-Negami, etc.). This work proposes instead to extract continuous d istributions of relaxation times from complex dielectric spectra by so lving a Fredholm integral equation using the Tikhonov regularization t echnique with a self-consistent choice of the regularization parameter . This method is stable with respect to the noise and resolves multipl e dynamical processes. An experimental example of salol adsorbed on mi croporous glass is analyzed.