PREPARATION AND CRYSTAL-STRUCTURE OF THE AMMONIUM COBALT CARBONATE HYDROXIDE HYDRATE (NH4)(2)CO-8(CO3)(6)(OH)(6)CENTER-DOT-4H(2)O

Authors
PETROV K DELEVA E GARCIAMARTINEZ O
Citation
K. Petrov et al., PREPARATION AND CRYSTAL-STRUCTURE OF THE AMMONIUM COBALT CARBONATE HYDROXIDE HYDRATE (NH4)(2)CO-8(CO3)(6)(OH)(6)CENTER-DOT-4H(2)O, Solid state ionics, 92(3-4), 1996, pp. 303-308
Citations number
7
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical
Journal title
Solid state ionics → ACNP
ISSN journal
01672738
Volume
92
Issue
3-4
Year of publication
1996
Pages
303 - 308
Database
ISI
SICI code
0167-2738(1996)92:3-4<303:PACOTA>2.0.ZU;2-9
Abstract
(NH4)(2)Co-8(CO3)(6)(OH)(6) . 4H(2)O was prepared by digesting Co-2(OH )(2)CO3 . xH(2)O in water solution of NH4HCO3. Chemical analyses, diff use reflectance spectroscopy and XRD data proved that this compound, l ike Na2Co8(CO3)(6)(OH)(6) . 6H(2)O and K2Co8(CO3)(6)(OH)(6) . 4H(2)O, is a derivative of the kambaldaite Na2Ni8(CO3)(6)(OH)(6) . 6H(2)O, a m ineral with an unique channel structure which had no other synthetic o r natural analogues.