G. Vanderlaan et al., MAGNETIC CIRCULAR-DICHROISM AND ORBITAL MOMENTUM COUPLING IN 4D PHOTOEMISSION FROM GD(0001), Physical review. B, Condensed matter, 53(10), 1996, pp. 5998-6001
Strong magnetic circular dichroism (MCD) has been observed in 4d core-
level photoemission (PE) from magnetized Gd(0001) metal, in agreement
with an atomic many-particle description. This solves a longstanding c
ontroversy on the correct interpretation of the 4d PE spectrum of Gd.
We show that MCD depends on the spin and orbital-momentum coupling in
the final state, leading to MCD effects of opposite sign for high and
low total angular momenta, respectively. The spin of the excited state
can be assigned from MCD, and we discuss its role in the lifetime bro
adening of PE peaks.