Ty. Makogon et al., STRUCTURE-H AND STRUCTURE-I HYDRATE EQUILIBRIUM DATA FOR 2,2-DIMETHYLBUTANE WITH METHANE AND XENON, Journal of chemical and engineering data, 41(2), 1996, pp. 315-318
Three-phase (ice + hydrate + vapor and liquid water + hydrate + vapor)
equilibrium data are presented for xenon structure I (sI) hydrate in
the temperature range 228-288 K. Four-phase (ice + hydrate + liquid hy
drocarbon + vapor and liquid water + hydrate + liquid hydrocarbon + va
por) equilibrium data are reported for structure H (sH) hydrates of xe
non + 2,2-dimethylbutane and methane + 2,2-dimethylbutane. The data fo
r both of the latter systems indicated two invariant five-phase points
(I + liquid water + sH + V + liquid hydrocarbon) at 273.15 K while th
e data for the water + xenon + 2,2-dimethylbutane system indicated an
additional quintuple point (liquid water + sI + sH + vapor + liquid hy
drocarbon) at 283.2 K.