STRUCTURE-H AND STRUCTURE-I HYDRATE EQUILIBRIUM DATA FOR 2,2-DIMETHYLBUTANE WITH METHANE AND XENON

Citation
Ty. Makogon et al., STRUCTURE-H AND STRUCTURE-I HYDRATE EQUILIBRIUM DATA FOR 2,2-DIMETHYLBUTANE WITH METHANE AND XENON, Journal of chemical and engineering data, 41(2), 1996, pp. 315-318
Citations number
18
Categorie Soggetti
Engineering, Chemical",Chemistry
ISSN journal
00219568
Volume
41
Issue
2
Year of publication
1996
Pages
315 - 318
Database
ISI
SICI code
0021-9568(1996)41:2<315:SASHED>2.0.ZU;2-R
Abstract
Three-phase (ice + hydrate + vapor and liquid water + hydrate + vapor) equilibrium data are presented for xenon structure I (sI) hydrate in the temperature range 228-288 K. Four-phase (ice + hydrate + liquid hy drocarbon + vapor and liquid water + hydrate + liquid hydrocarbon + va por) equilibrium data are reported for structure H (sH) hydrates of xe non + 2,2-dimethylbutane and methane + 2,2-dimethylbutane. The data fo r both of the latter systems indicated two invariant five-phase points (I + liquid water + sH + V + liquid hydrocarbon) at 273.15 K while th e data for the water + xenon + 2,2-dimethylbutane system indicated an additional quintuple point (liquid water + sI + sH + vapor + liquid hy drocarbon) at 283.2 K.