REFINEMENT OF THE CRYSTAL-STRUCTURE OF SR3HG2

Citation
C. Druska et al., REFINEMENT OF THE CRYSTAL-STRUCTURE OF SR3HG2, Zeitschrift fur anorganische und allgemeine Chemie, 622(3), 1996, pp. 401-404
Citations number
73
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
622
Issue
3
Year of publication
1996
Pages
401 - 404
Database
ISI
SICI code
0044-2313(1996)622:3<401:ROTCOS>2.0.ZU;2-O
Abstract
Mixtures of strontium and mercury in molar ratios of 7:3 have been ann ealed for 20 days at 520 degrees C. From the pure product Sr3Hg2 singl e crystals have been obtained. Sr3Hg2 crystallizes in the U3Si2 type o f structure (space group P4/mbm); the cell constants are a = 8.883 (2) Angstrom and c = 4.553(1) Angstrom. All of the Hg atoms are involved in Hg-2 dumbbells with Hg-Hg distances of 3.41 Angstrom.