Some recent contributions of Mossbauer spectrometry to the characteriz
ation of nanostructured materials are described. The statistically mea
ningful information conveyed by Mossbauer spectra and the atomic scale
sensitivity of the method are invaluable for studying problems specif
ic to the nanometer range which are often difficult to investigate wit
h more conventional techniques. Phenomena that occur during the synthe
sis of nanomaterials by ball milling, studies of grain boundaries, inv
estigation of thermal stability of bulk materials are discussed.