REDUCTION OF 1,1-DIFLUORO-1-ALKEN-3-OLS WITH LITHIUM TETRAHYDROALUMINATE - APPLICATION TO THE SYNTHESIS OF 1,1-DIFLUORO-2-ALKENES AND 2-ALKENALS

Citation
F. Tellier et R. Sauvetre, REDUCTION OF 1,1-DIFLUORO-1-ALKEN-3-OLS WITH LITHIUM TETRAHYDROALUMINATE - APPLICATION TO THE SYNTHESIS OF 1,1-DIFLUORO-2-ALKENES AND 2-ALKENALS, Journal of fluorine chemistry, 76(2), 1996, pp. 181-185
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
00221139
Volume
76
Issue
2
Year of publication
1996
Pages
181 - 185
Database
ISI
SICI code
0022-1139(1996)76:2<181:RO1WLT>2.0.ZU;2-S
Abstract
The reduction of 1,1-difluoro-1-alken-3-ols with lithium tetrahydroalu minate is described. The 1-fluoro-1-alken-3-ols obtained can be transf ormed to enals or difluoromethylated allylic derivatives.