X-ray photoelectron spectroscopy (XPS) measurements show that Ce occur
s in photorefractive Sr0.61Ba0.39Nb2O6 (SBN) crystals mainly in the va
lence state 3+. We give arguments that Ce-3+/4+ is the photorefractive
center in SBN:Ce with a typical concentration ratio c(Ce?(3+))/c(Ce?(
4+)) = 600. Quantitative analysis of the XPS data yields a Ce distribu
tion coefficient of about 0.6 +/- 0.3.