CHANGE OF TOPOLOGY OF THE CHEMICAL INTERACTION STAGE AS A TOOL FOR THE STEREOSELECTIVITY CONTROL OF PTC REACTIONS

Authors
AFONKIN AA SHUMEIKO AE POPOV AF
Citation
Aa. Afonkin et al., CHANGE OF TOPOLOGY OF THE CHEMICAL INTERACTION STAGE AS A TOOL FOR THE STEREOSELECTIVITY CONTROL OF PTC REACTIONS, Russian chemical bulletin, 44(11), 1995, pp. 2006-2011
Citations number
29
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
44
Issue
11
Year of publication
1995
Pages
2006 - 2011
Database
ISI
SICI code
1066-5285(1995)44:11<2006:COTOTC>2.0.ZU;2-S
Abstract
The relationship between the rate-limiting step of PTC and the site of the chemical interaction stage has been established for the cyclotrip hosphazenes phenolysis reaction in liquid-liquid systems. Transfer of the site of the phenolysis of mono(aryloxy)cyclotriphosphazenes from t he bulk of the organic phase to the interface results in a change in t he ratio of the products of the reaction of cis- and trans- isomers of bis(aryloxy)cyclotriphosphazenes.