COMPLEXES OF LANTHANUM WITH RADICAL-ANIONS OF 2,2-BIPYRIDYL AND 3,6-DI-TERT-BUTYL-O-BENZOQUINONE

Authors
FEDUSHKIN IL NEVODCHIKOV VI BOCHKAREV MN
Citation
Il. Fedushkin et al., COMPLEXES OF LANTHANUM WITH RADICAL-ANIONS OF 2,2-BIPYRIDYL AND 3,6-DI-TERT-BUTYL-O-BENZOQUINONE, Russian chemical bulletin, 44(11), 1995, pp. 2185-2186
Citations number
2
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
44
Issue
11
Year of publication
1995
Pages
2185 - 2186
Database
ISI
SICI code
1066-5285(1995)44:11<2185:COLWRO>2.0.ZU;2-S
Abstract
Complexes of a rare-earth element containing only one radical-anion li gand have been synthesized and isolated in pure states for the first t ime. The LaI2(bPY)(THF)(3) complex has been prepared from [LaI2(THF)(3 )](2)(C10H8) and 2,2-bipyridyl in DME. The semiquinone complex LaI2(SQ )(THF)(3) has been obtained by reaction of lanthanum iodide with 3,6-d i-tert-butyl-o-benzoquinone in THF in the presence of lanthanum powder . ESR spectra of the complexes have been studied.