INTRODUCTION OF 2 BENZYL GROUPS TO C-60 BY USING THE COLLMAN REAGENT

Authors
MIKI S KITAO M FUKUNISHI K
Citation
S. Miki et al., INTRODUCTION OF 2 BENZYL GROUPS TO C-60 BY USING THE COLLMAN REAGENT, Tetrahedron letters, 37(12), 1996, pp. 2049-2052
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
12
Year of publication
1996
Pages
2049 - 2052
Database
ISI
SICI code
0040-4039(1996)37:12<2049:IO2BGT>2.0.ZU;2-T
Abstract
Addition of C-60 to a suspension of the Collman reagent in THF gave a strongly colored but almost transparent solution. Treatment of the res ulting solution with benzyl bromide gave a C-60 derivative possessing two benzyl groups. The H-1-NMR as well as the C-13-NMR of the product indicated that the reaction site was 1,4-position.