ON REACTION OF ENAMIDES WITH ACETYL NITRATE

Authors
MORZYCKI JW WILCZEWSKA AZ LOTOWSKI Z
Citation
Jw. Morzycki et al., ON REACTION OF ENAMIDES WITH ACETYL NITRATE, Tetrahedron letters, 37(12), 1996, pp. 2079-2082
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
12
Year of publication
1996
Pages
2079 - 2082
Database
ISI
SICI code
0040-4039(1996)37:12<2079:OROEWA>2.0.ZU;2-F
Abstract
The reactions of four steroidal enamides with acetyl nitrate were stud ied. The nitronium ion attacks the terminal carbon atom of the enamide moiety. Further transformations of the unsaturated nitro derivative c onsist of an allylic oxidation or a Ne+-type reaction.