L. Ramos et al., COMPATIBILITY BETWEEN SOLID PARTICLES AND A LAMELLAR PHASE - A CRUCIAL ROLE OF THE MEMBRANE INTERACTIONS, Journal of physical chemistry, 100(11), 1996, pp. 4533-4537
From previous studies, we know that Helfrich-stabilized smectic phases
can incorporate solid particles of typical size 10 nm between their m
embranes; the incorporation of magnetic particles yields a ''ferrosmec
tic'' phase. We present here a study of the compatibility between such
solid particles and a lamellar phase versus the interactions between
membranes. The type of stabilizing forces, from purely electrostatic t
o purely entropic, is varied via the concentration of salt (NaCl) in a
swollen lamellar phase. The experimental results reported in this pap
er show that the Helfrich phases can incorporate particles within thei
r lamellar matrix, whereas particles are excluded from the electrostat
ic phases. A semiquantitative interpretation based on considerations a
bout the interactions between particles and membranes is given.