COMPATIBILITY BETWEEN SOLID PARTICLES AND A LAMELLAR PHASE - A CRUCIAL ROLE OF THE MEMBRANE INTERACTIONS

Citation
L. Ramos et al., COMPATIBILITY BETWEEN SOLID PARTICLES AND A LAMELLAR PHASE - A CRUCIAL ROLE OF THE MEMBRANE INTERACTIONS, Journal of physical chemistry, 100(11), 1996, pp. 4533-4537
Citations number
24
Categorie Soggetti
Chemistry Physical
ISSN journal
00223654
Volume
100
Issue
11
Year of publication
1996
Pages
4533 - 4537
Database
ISI
SICI code
0022-3654(1996)100:11<4533:CBSPAA>2.0.ZU;2-B
Abstract
From previous studies, we know that Helfrich-stabilized smectic phases can incorporate solid particles of typical size 10 nm between their m embranes; the incorporation of magnetic particles yields a ''ferrosmec tic'' phase. We present here a study of the compatibility between such solid particles and a lamellar phase versus the interactions between membranes. The type of stabilizing forces, from purely electrostatic t o purely entropic, is varied via the concentration of salt (NaCl) in a swollen lamellar phase. The experimental results reported in this pap er show that the Helfrich phases can incorporate particles within thei r lamellar matrix, whereas particles are excluded from the electrostat ic phases. A semiquantitative interpretation based on considerations a bout the interactions between particles and membranes is given.