CONVENTIONAL AND MANIPULATED GROWTH OF CU CU(111)/

Citation
W. Wulfhekel et al., CONVENTIONAL AND MANIPULATED GROWTH OF CU CU(111)/, Surface science, 348(3), 1996, pp. 227-242
Citations number
65
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
00396028
Volume
348
Issue
3
Year of publication
1996
Pages
227 - 242
Database
ISI
SICI code
0039-6028(1996)348:3<227:CAMGOC>2.0.ZU;2-I
Abstract
Molecular beam epitaxy of Cu on Cu(111) was studied using thermal ener gy He scattering, in the temperature range between 100 and 450 K. Thre e-dimensional growth was observed in the whole temperature range. To d etermine the onset of various diffusion processes, submonolayer films formed by deposition at low temperature were annealed. Annealing proce eds in two steps. The first step is interpreted as a change in island shape, the second as Ostwald-ripening. A comparison with homoepitaxy o n Pt(111) and Ag(111) is made. Growth manipulation was carried out by artificially increasing the island number density via intervention in the nucleation stage of each layer. The procedures applied were temper ature reduction during nucleation as well as pulsed ion bombardment. T hese techniques enabled the convenient growth of good quality films co nsisting of a large number of monolayers. Finally, the use of oxygen a s a surfactant modifying the growth mode was investigated. Under some growth conditions, pre-exposure of the surface to oxygen was found to induce weak He-intensity oscillations during deposition. The quality o f the films grown in this way was, however, low.