Citation
Y. Ruina et al., SYNTHESIS, STRUCTURE AND CHARACTERIZATION OF BINUCLEAR SILVER(I) COMPLEXES, Transition metal chemistry, 21(1), 1996, pp. 28-30
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285
→ ACNP
Volume
21
Issue
1
Year of publication
1996
Pages
28 - 30
Database
ISI
SICI code
0340-4285(1996)21:1<28:SSACOB>2.0.ZU;2-T
Abstract
Two binuclear Ag-1 complexes, [{Ag(dppp)}(2)] (NO3)(2) (1) and [{Ag(dp
pb)}(2)(NO3)](2) (2) (dppp = Ph(2)P(CH2)(3)PPh(2), dppb = Ph(2)P(CH2)(
4)PPh(2)], were synthesized and characterized by elemental analysis, t
.g., i.r. and P-31-n.m.r. spectra. Single crystals of complex (2) were
obtained from MeOH-CHCl3. The X-ray crystal structure shows that the
dppb ligand is bidentate, with two ligands bridging two metal ions to
form a centrosymmetric dimer.