LIGAND-FIELD PARAMETERS IN PENTAAMMINE COMPLEXES OF CHROMIUM(III) WITH A CARBON-OXYGEN OR PHOSPHORUS-OXYGEN DONOR

Authors
RAJENDRAM CRA HOGGARD PE
Citation
Cra. Rajendram et Pe. Hoggard, LIGAND-FIELD PARAMETERS IN PENTAAMMINE COMPLEXES OF CHROMIUM(III) WITH A CARBON-OXYGEN OR PHOSPHORUS-OXYGEN DONOR, Transition metal chemistry, 21(1), 1996, pp. 61-63
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
21
Issue
1
Year of publication
1996
Pages
61 - 63
Database
ISI
SICI code
0340-4285(1996)21:1<61:LPIPCO>2.0.ZU;2-3
Abstract
Coordination of oxyphosphorus ligands to pentaamminechromium(III) lowe rs the ligand field strength of the ammines to a much greater extent t han trichloroacetate. This presumably signifies a weaker metal-nitroge n bond, and may contribute to the reluctance of the amines in aminopho sphonate ligands to coordinate.