Rw. Hay et R. Bradshaw, COBALT(III) COMPLEXES OF -10-OXIMINO-3,9-DIMETHYL-4,8-DIAZAUNDECA-3,8-DIENE, Transition metal chemistry, 21(1), 1996, pp. 64-66
The pseudo-macrocyclic dioxime ligand [(1) = LH] has been synthesized.
A variety of cobalt(III) complexes, trans-[CoLX(2)], have been prepar
ed and characterized (X = Cl, Br, NO2, NCS or N-3) and [CoLCl(NO2)]. V
is. and i.r. spectra of the complexes are reported and aspects of the
solution chemistry of the complexes studied.