A HYDROGEN-BONDED DICHLOROMETHANE-PERCHLORATE-WATER CHANNEL IN THE CRYSTAL-STRUCTURE OF O-TOLYL)(2))CL-]CENTER-DOT-CH2CL2-CENTER-DOT-H2O(] [CLO4)

Authors
CHURCHILL MR KRAJKOWSKI LM HUYNH MHV TAKEUCHI KJ
Citation
Mr. Churchill et al., A HYDROGEN-BONDED DICHLOROMETHANE-PERCHLORATE-WATER CHANNEL IN THE CRYSTAL-STRUCTURE OF O-TOLYL)(2))CL-]CENTER-DOT-CH2CL2-CENTER-DOT-H2O(] [CLO4), Journal of chemical crystallography, 26(1), 1996, pp. 67-73
Citations number
5
Categorie Soggetti
Crystallography,Spectroscopy
Journal title
Journal of chemical crystallography → ACNP
ISSN journal
10741542
Volume
26
Issue
1
Year of publication
1996
Pages
67 - 73
Database
ISI
SICI code
1074-1542(1996)26:1<67:AHDCIT>2.0.ZU;2-Y
Abstract
The complex cis-[Ru(bpy)(2){PPh(o-tolyl)(2)}Cl+][ClO4-] crystallized f rom a solution in dichloromethane as the dichioromethane-water solvate . The structure was refined to R = 4.5% for those 2433 reflections wit h \F-o\ > 6 sigma(\F-o\). The octahedral Ru(II) cation is associated w ith metal-ligand distances as follows: Ru-Cl = 2.434(3)Angstrom, Ru-PP h(o-tol)(2) = 2.382(2)Angstrom, and Ru-N = 2.037(7) - 2.088(7)Angstrom . The structure is stabilized by a hydrogen-bonded CH2Cl2 ... ClO4-... H2O channel which incorporates adventitious water of crystallization.