A pot experiment was conducted to investigate the boron (B) bioavailab
ility to corn seedlings (Zea mays L) in an artificial soil mix produce
d from alkaline coal fly ash and sewage sludge under greenhouse condit
ions. Sludge was amended with ash at an application rate of 0, 5, 10,
35, and 50% (w/w), and each mixture was then mixed with a loamy soil a
t either 1:1 or 1:5 (v/v). Both water soluble B (WS-B) and hot water s
oluble B (HWS-B) increased with an increase in the fly ash amendment r
ate. Plant tissue B contents also increased according to the rate of a
sh amendment, and at high ash application rates, more than 70% of the
tissue B content was accumulated in leaves. Among the plant organs, B
contents of young leaves showed a better correlation with HWS-B conten
ts than with WS-B, and HWS-B gave a better indication on soil B availa
bility. Boron toxicity symptoms in leaf margins were observed in 50% a
nd 35% ash-amended sludge at 1:1 soil-mixing ratio, with shoot [B] rea
ching 225 mg kg(-1). However, a significant yield reduction was observ
ed only at 50% ash-amended sludge at 1:1 v/v, indicating that factors
in addition to B might affect plant growth.