A SIMPLE ROUTE TO ENANTIOPURE FLUOROCYCLOHEXENONES

Authors
WEINMANN H WINTERFELDT E
Citation
H. Weinmann et E. Winterfeldt, A SIMPLE ROUTE TO ENANTIOPURE FLUOROCYCLOHEXENONES, Synthesis, (3), 1996, pp. 357
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
3
Year of publication
1996
Database
ISI
SICI code
0039-7881(1996):3<357:ASRTEF>2.0.ZU;2-1
Abstract
The 4-fluoro substituted cyclohexadienone 10 was shown to undergo a ve ry efficient differentiation of enantiotopic double bonds in a Diels-A lder cycloaddition process. Epoxidation followed by thermal retro reac tion generated the enantiopure fluorocyclohexenone 13.