CHEMOSELECTIVE SYNTHESIS OF TRIFLUOROMETHYLVINYL SULFOXIDES AND SULFONES THROUGH OXIDATION OF CORRESPONDING SULFIDES

Citation
Jp. Begue et al., CHEMOSELECTIVE SYNTHESIS OF TRIFLUOROMETHYLVINYL SULFOXIDES AND SULFONES THROUGH OXIDATION OF CORRESPONDING SULFIDES, Synthesis, (3), 1996, pp. 399
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00397881
Issue
3
Year of publication
1996
Database
ISI
SICI code
0039-7881(1996):3<399:CSOTSA>2.0.ZU;2-Q
Abstract
At low temperatures, perfluoro-cis-2,3-dialkyloxaziridines 4 oxidize 1 -trifluoromethylvinyl sulfides 1 to the corresponding sulfoxides 2 in quantitative yields. By using 3-chloroperoxybenzoic acid, or the same oxaziridines at room temperature, sulfones 3 are formed exclusively.