CHEMOSELECTIVE SYNTHESIS OF TRIFLUOROMETHYLVINYL SULFOXIDES AND SULFONES THROUGH OXIDATION OF CORRESPONDING SULFIDES

Authors
BEGUE JP MBIDA A BONNETDELPON D NOVO B RESNATI G
Citation
Jp. Begue et al., CHEMOSELECTIVE SYNTHESIS OF TRIFLUOROMETHYLVINYL SULFOXIDES AND SULFONES THROUGH OXIDATION OF CORRESPONDING SULFIDES, Synthesis, (3), 1996, pp. 399
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
3
Year of publication
1996
Database
ISI
SICI code
0039-7881(1996):3<399:CSOTSA>2.0.ZU;2-Q
Abstract
At low temperatures, perfluoro-cis-2,3-dialkyloxaziridines 4 oxidize 1 -trifluoromethylvinyl sulfides 1 to the corresponding sulfoxides 2 in quantitative yields. By using 3-chloroperoxybenzoic acid, or the same oxaziridines at room temperature, sulfones 3 are formed exclusively.