C. Park et al., ENHANCEMENT OF THE NO2-SENSING CAPABILITY OF COPPER PHTHALOCYANINE BYMEASURING THE RELATIVE RESISTANCE CHANGE, Sensors and actuators. B, Chemical, 30(1), 1996, pp. 23-27
The gas-sensing properties of copper phthalocyanine (CuPc) thin films
have been measured for NO2 concentrations of 1 to 10 parts per million
(ppm). The CuPc films thermally evaporated on glass substrates appear
to have an cy-form polycrystalline structure. Most measurements of ga
s sensitivity are done with heat-cleaned sensing elements to reduce th
e instability of CuPc resistance. We have established unambiguously th
at a significant enhancement of detectivity can be accomplished by con
verting the resistance to a normalized figure, i.e., the relative resi
stance. Good sensitivity to as low as 1 ppm has been reproducibly achi
eved.