Kc. Kalra et al., KINETICS OF GROWTH OF ANODIC OXIDE-FILMS ON TITANIUM, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 35(4), 1996, pp. 294-299
Steady state kinetic data for the formation of anodic oxide films on t
itanium in mixed solution of aqueous electrolyte (disodium hydrogen ph
osphate) with diethylene glycol at different current density sets and
at different temperatures have been obtained. Various parameters of an
odic oxidation have been evaluated using Dewald's theory. The entrance
barrier energy has been found less than the corresponding diffusion b
arrier energy and this suggests that the rate-controlling step in the
kinetics of growth of anodic film is the ionic movement across the fil
m and not at the metal/oxide interface.