The reflection of linear acoustic waves propagating in a very compress
ible, low heat diffusing, supercritical fluid (CO2) is studied by solv
ing the non-linear Navier-Stokes (NS) equations written for a near-cri
tical van der Waals gas. It is shown that close enough to the critical
point, the reflection rules of acoustic waves on thermostated boundar
ies are inverted compared to those usually observed in ideal gases. Th
is phenomenon has been put in evidence by numerical simulations and it
s mechanism is shown to be due to the strong contraction or expansion
of a hypercompressible thermal adaptation boundary layer. The asymptot
ic analysis of the equations gives the order of magnitude of the dista
nce to the critical point where the inversion occurs. This transition
corresponds to the transition to the so-called Acoustically Saturated
Regime, in which the characteristic time-scale of heat transfer reache
s its lower limit (i.e. the acoustic typical time).