A study of He-3 in porous glasses is performed in which the observed c
hemical shifts and lineshapes are attributed to the local magnetic fie
ld distribution in the pores and to the distribution of pore shapes. T
he observed relaxation times T-1 and T-2 are explained by the residual
oxygen concentration in the pores and by the diffusion of He-3 in the
inhomogeneous local field, respectively. The study indicates that in
principle sample tubes containing He-3 in the pores as a built-in lock
substance could be produced but the production is not straightforward
. He-3 proves to be an ideal nucleus for studying the shape of void st
ructures in solids. (C) 1996 Academic Press, Inc.