LUMINESCENT RHENIUM(I) CARBON WIRES - SYNTHESIS, PHOTOPHYSICS, AND ELECTROCHEMISTRY - X-RAY CRYSTAL-STRUCTURE OF (T)BU(2)BPY)(CO)(3)(C-CC-C)RE((T)BU(2)BPY)(CO)(3)]

Citation
Vww. Yam et al., LUMINESCENT RHENIUM(I) CARBON WIRES - SYNTHESIS, PHOTOPHYSICS, AND ELECTROCHEMISTRY - X-RAY CRYSTAL-STRUCTURE OF (T)BU(2)BPY)(CO)(3)(C-CC-C)RE((T)BU(2)BPY)(CO)(3)], Organometallics, 15(6), 1996, pp. 1740-1744
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
02767333
Volume
15
Issue
6
Year of publication
1996
Pages
1740 - 1744
Database
ISI
SICI code
0276-7333(1996)15:6<1740:LRCW-S>2.0.ZU;2-J
Abstract
t)Bu(2)bpy)(CO)(3)(C=CC=C)Re((t)Bu(2)bpy)(CO)(3)], which consists of a n extended linear O=C-Re-C=C-C=C-Re-C=O unit, has been synthesized by the coupling of two [Re((t)Bu(2)bpy)(CO)(3)(C=CH)] units; both of thes e complexes and the related [Re((t)Bu(2)bpy)(CO)(3)(C=CC6H13)] complex are shown to exhibit rich photophysical behavior. The electrochemical properties of these complexes have also been studied. The X-ray cryst al structure of (t)Bu(2)bpy)(CO)(3)(C=CC=C)Re((t)Bu(2)bpy)(CO)(3)] has been determined.