MIXED-METAL CLUSTER CHEMISTRY .4. SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF CP(3)W(3)IR(4)(MU-H)(CO)(12)

Authors
WATERMAN SM HUMPHREY MG HOCKLESS DCR
Citation
Sm. Waterman et al., MIXED-METAL CLUSTER CHEMISTRY .4. SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF CP(3)W(3)IR(4)(MU-H)(CO)(12), Organometallics, 15(6), 1996, pp. 1745-1748
Citations number
50
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
6
Year of publication
1996
Pages
1745 - 1748
Database
ISI
SICI code
0276-7333(1996)15:6<1745:MCC.SA>2.0.ZU;2-Y
Abstract
Heating Cp(2)W(2)Ir(2)(CO)(10) with triphenylamine in refluxing tetrah ydrofuran affords CP3W3Ir4(mu-H)(CO)(12) (I) in poor yield; an X-ray s tructural study reveals that the molecule consists of a trigonal bipyr amidal CpW{Ir(CO)(2)}(4) unit bicapped by CpW(CO)(2) fragments.