FLEXIBILITY OF THE MEMBRANES IN A DOPED SWOLLEN LAMELLAR PHASE

Citation
V. Ponsinet et P. Fabre, FLEXIBILITY OF THE MEMBRANES IN A DOPED SWOLLEN LAMELLAR PHASE, Journal of physical chemistry, 100(12), 1996, pp. 5035-5038
Citations number
21
Categorie Soggetti
Chemistry Physical
ISSN journal
00223654
Volume
100
Issue
12
Year of publication
1996
Pages
5035 - 5038
Database
ISI
SICI code
0022-3654(1996)100:12<5035:FOTMIA>2.0.ZU;2-3
Abstract
We have measured the flexibility kappa of the membranes of a quaternar y lamellar phase of periodicity d, without and with particles included between the layers. We show that an increase in cosurfactant amount i n the membranes leads to a decrease of the flexibility constant kappa, for the two studied systems. On the other hand, the membrane flexibil ity kappa is shown to be hardly different in nondoped and doped (ferro smectic) systems. This implies that the enhanced value of the elastic bending modulus K, observed when the lamellar phase is doped with part icles, cannot be attributed to a simple hardening of the membranes. Th is leads us to question the well-known relationship between the elasti city of a lamellar phase and the elasticity of its constituting layers : K = kappa/d, in the case of ferrosmectic phases.