H. Buhmann et al., CREATION AND ANNIHILATION OF NEGATIVELY CHARGED EXCITONS IN GAAS QUANTUM-WELLS, Nuovo cimento della Societa italiana di fisica. D, Condensed matter,atomic, molecular and chemical physics, biophysics, 17(11-12), 1995, pp. 1395-1400
The electroluminescence of p-i-n GaAs double-barrier resonant tunnelli
ng diodes has been investigated for various concentrations of free car
riers (either holes or electrons) in the quantum well (QW). For these
structures it is possible to change the relative electron or hole dens
ity quasi-continuously with applied bias-voltage. New low-temperature
excitonic recombinations are identified in the electroluminescence spe
ctra. Continuous variation of the carrier density in the quantum well
from a hole-rich into an electron-rich environment leads to the observ
ation of positively charged excitons (X(2)(+)), neutral excitons (X),
negatively charged excitons (X(-)) and finally an unbound electron-hol
e recombination. An increased temperature causes the dissociation of t
he charged excitons in favour of the neutral heavy-hole free exciton X
. In high magnetic fields the unbound electron-hole recombination is t
ransferred into an excitonic recombination.