CATALYTIC BEHAVIOR OF A MAGNESIUM-OXIDE SUPPORTED POLYSILAZANE RUTHENIUM COMPLEX FOR THE OXIDATION OF INDENE WITH MOLECULAR-OXYGEN TO INDANONES

Authors
WANG TJ SUN FY HUANG MY JIANG YY
Citation
Tj. Wang et al., CATALYTIC BEHAVIOR OF A MAGNESIUM-OXIDE SUPPORTED POLYSILAZANE RUTHENIUM COMPLEX FOR THE OXIDATION OF INDENE WITH MOLECULAR-OXYGEN TO INDANONES, Reaction kinetics and catalysis letters, 57(1), 1996, pp. 147-152
Citations number
8
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
57
Issue
1
Year of publication
1996
Pages
147 - 152
Database
ISI
SICI code
0133-1736(1996)57:1<147:CBOAMS>2.0.ZU;2-I
Abstract
A new magnesium oxide supported polysilazane ruthenium complex has bee n prepared and found to be capable of catalyzing the oxygenation of in dene in 62.9% conversion to indanones without by-products under mild c onditions, i.e. 1 atm oxygen and 80 degrees C. The supported ruthenium complex was effective without need for a cocatalyst. Also, it can be reused several times without apparent loss of activity.