SORPTION AND DESORPTION OF THORIUM FROM AQUEOUS-SOLUTIONS BY MONTMORILLONITE

Authors
Citation
H. Akcay et S. Kilinc, SORPTION AND DESORPTION OF THORIUM FROM AQUEOUS-SOLUTIONS BY MONTMORILLONITE, Journal of radioanalytical and nuclear chemistry, 212(3), 1996, pp. 173-185
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Analytical","Nuclear Sciences & Tecnology
ISSN journal
02365731
Volume
212
Issue
3
Year of publication
1996
Pages
173 - 185
Database
ISI
SICI code
0236-5731(1996)212:3<173:SADOTF>2.0.ZU;2-H
Abstract
The sorption and desorption of thorium on a West Anatolian montmorillo nite has been studied by application of a batch technique. Experimenta l procedures are outlined and results for thorium contacted with montm orillonite are reported and discussed. The thorium concentration range was between 200-4000 ppm (8.5x1(-4) - 1.7x10(-2)M). The sorption and desorption coefficients varied between 1.586-0.216 ml g(-1) and 0.829- 0.168 ml g(-1), respectively, and sorption was not fully reversible. T he data could be fitted to Freundlich and Langmuir isotherms. The quan tity of the sorbed thorium was much lower than its theoretical CEC. Th is was attributed to a blocking of montmorillonite's CEC by thorium is lands in the interlayer.