H. Akcay et S. Kilinc, SORPTION AND DESORPTION OF THORIUM FROM AQUEOUS-SOLUTIONS BY MONTMORILLONITE, Journal of radioanalytical and nuclear chemistry, 212(3), 1996, pp. 173-185
The sorption and desorption of thorium on a West Anatolian montmorillo
nite has been studied by application of a batch technique. Experimenta
l procedures are outlined and results for thorium contacted with montm
orillonite are reported and discussed. The thorium concentration range
was between 200-4000 ppm (8.5x1(-4) - 1.7x10(-2)M). The sorption and
desorption coefficients varied between 1.586-0.216 ml g(-1) and 0.829-
0.168 ml g(-1), respectively, and sorption was not fully reversible. T
he data could be fitted to Freundlich and Langmuir isotherms. The quan
tity of the sorbed thorium was much lower than its theoretical CEC. Th
is was attributed to a blocking of montmorillonite's CEC by thorium is
lands in the interlayer.