(SOLID PLUS LIQUID) PHASE-EQUILIBRIA AND SOLID-COMPOUND FORMATION IN (TRICHLOROMETHANE PLUS CYCLOHEXANONE, OR BUTANONE, OR 1-METHYL-2-PYRROLIDINONE)

Citation
Gq. Che et al., (SOLID PLUS LIQUID) PHASE-EQUILIBRIA AND SOLID-COMPOUND FORMATION IN (TRICHLOROMETHANE PLUS CYCLOHEXANONE, OR BUTANONE, OR 1-METHYL-2-PYRROLIDINONE), Journal of Chemical Thermodynamics, 28(2), 1996, pp. 159-165
Citations number
4
Categorie Soggetti
Chemistry Physical
ISSN journal
00219614
Volume
28
Issue
2
Year of publication
1996
Pages
159 - 165
Database
ISI
SICI code
0021-9614(1996)28:2<159:(PLPAS>2.0.ZU;2-U
Abstract
(Solid + liquid) phase diagrams have been constructed for (trichlorome thane + cyclohexanone, or butanone, or 1-methyl-2-pyrrolidinone). Soli d addition compounds form with the empirical formulae: CHCl3 . C6H10O, CHCl3 . C5H9NO, (CHCl3)(2) . C4H8O, (CHCl3)(2) . C6H10O, and (CHCl3)( 2) . C5H9NO. Compound formation is attributed to charge-transfer inter action for the first two compounds, and to hydrogen bonding for the la st three. (C) 1996 Academic Press Limited