METHYL CELLULOSE STABILIZED POLYANILINE DISPERSIONS

Citation
D. Chattopadhyay et Bm. Mandal, METHYL CELLULOSE STABILIZED POLYANILINE DISPERSIONS, Langmuir, 12(6), 1996, pp. 1585-1588
Citations number
41
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
07437463
Volume
12
Issue
6
Year of publication
1996
Pages
1585 - 1588
Database
ISI
SICI code
0743-7463(1996)12:6<1585:MCSPD>2.0.ZU;2-M
Abstract
Methyl cellulose has been used as a stabilizer in the oxidative disper sion polymerization of aniline using ammonium persulfate oxidant. The dispersion polymerization is unsuccessful in water but successfully ef fected in aqueous alcohol media. Evidence has been presented that the stabilizer incorporation in polyaniline is increasingly facilitated as the alcohol concentration of the medium is increased. Particle morpho logy changes from long needle-shaped to oblong (doublets of spheres) o r spherical as the alcohol concentration is increased from 30% to 70%.