A new type of nonhydrogenated diamond-like carbon film defined as amor
phous diamond (a-D) can be deposited from Enhanced Are carbon source o
n various substrate materials such as Si, high speed steel (HSS) and W
C at room temperature. The role of evaporation and condensation of hig
hly ionized carbon plasma has been investigated in this study. Experim
ental results show that significant relationships exist between the en
ergy distribution of the flux species, the particle surface interactio
ns and the microstructure and mechanical properties of the a-D films.
Films deposited in optimum conditions at growth rate of 6 mu m h(-1) e
xhibit high hardness and Young's modulus, with peak values measured by
the nanoindentation technique of around 95 GPa and 1150 GPa respectiv
ely, approaching those of natural diamond. Furthermore, the specific p
ossibility of the modified are technique compared with other physical
vapor deposition processes leads to excellent adhesion on various subs
trates. Scratch test measurements reveal values of 50 N-80 N on HSS an
d WC substrates respectively.