1ST SHELL SUBSTITUTION EFFECTS - DIGLYCIDYL ETHER OF BISPHENOL A CURED WITH 4,4'-DIAMINODIPHENYLMETHANE

Authors
NOUREDDINI H TIMM DC
Citation
H. Noureddini et Dc. Timm, 1ST SHELL SUBSTITUTION EFFECTS - DIGLYCIDYL ETHER OF BISPHENOL A CURED WITH 4,4'-DIAMINODIPHENYLMETHANE, Polymer gels and networks, 2(3-4), 1994, pp. 205-217
Citations number
32
Categorie Soggetti
Polymer Sciences
Journal title
Polymer gels and networks → ACNP
ISSN journal
09667822
Volume
2
Issue
3-4
Year of publication
1994
Pages
205 - 217
Database
ISI
SICI code
0966-7822(1994)2:3-4<205:1SSE-D>2.0.ZU;2-5
Abstract
First shell substitution effects were incorporated into a kinetic reac tion model descriptive of the polymerization of an epoxy resin formula ted from diglycidyl ether of bisphenol A and 4,4'-diaminodiphenylmetha ne. Analysis of population density distribution dynamics for the harde ner and several oligomers in the sol fraction showed that the reactivi ty of secondary amino hydrogens is less than the reactivity of primary amino hydrogens.