Polymers have emerged as an important class of materials for applicati
ons in photonics. In this review, a brief background is presented on p
hotonics and nonlinear optical processes, the latter providing many of
the operational functions for the photonics technology. Nonlinear opt
ical processes in polymeric materials are discussed along with the nee
ded structural requirements. The three types of nonlinear polymeric sy
stems discussed are: (i) chi(2) materials; (ii) chi(3) materials and (
iii) photorefractive polymers. The photorefractive polymeric systems u
tilize the combined action of photoconductivity and nonlinear optical
effect. New developments using sol-gel processed inorganic glass: poly
mer composites for nonlinear optics are discussed.