Nanocrystalline phases can be formed during crystallization of amorpho
us alloys annealed isothermally below the crystallization temperature.
We present magnetic susceptibility data on this transformation. Magne
tic measurements are able to detect the onset of the transformation of
amorphous Ni-P alloys much earlier than differential scanning calorim
etry. The transformation kinetics are analyzed by means of the Avrami
plot based on the Johnson-Mehl-Avrami equation. The kinetics of furthe
r solid state reactions in the nanostructured material can be investig
ated similarly.