SPECTRAL PROPERTIES OF ER3-DOPED GALLIUM LANTHANUM SULFIDE GLASS()

The spectral properties of chalcogenide glass 0.7Ga(2)S(3):0.3La(2)S(3 ) (Ga:La:S) doped with Er3+ are presented and discussed. Emission and adsorption spectra and lifetimes of energy levels have been measured. The 2.7 mu m emission of Er3+ has been observed from chalcogenide glas s for the first time. Radiative and non-radiative transition rates are calculated and compared with the measured lifetimes of interesting en ergy levels. Comparing this glass with Er3+-doped silica glasses, it i s shown that the absorption and emission cross-sections of Er3+-doped Ga:La:S are around 2.5 times higher, radiative transitions rates are a round five times higher due to its higher refractive index, while mult iphonon non-radiative decay rates are around three orders lower due to its much lower phonon energy. Furthermore, the inverse energy transfe r process in Er3+:Ga:La:S glass may have significant implications for the operation of Er3+:Ga:La:S devices. These spectral properties, alon g with the higher solubility for rare earth-ions in Ga:La:S, make this glass a good candidate for new applications.