A WHITLOCKITE-LIKE CALCIUM COPPER PHOSPHATE

Authors
YANOV OV MOROZOV VA VIETING BN IVANOV LN LAZORYAK BI
Citation
Ov. Yanov et al., A WHITLOCKITE-LIKE CALCIUM COPPER PHOSPHATE, Materials research bulletin, 29(12), 1994, pp. 1307-1314
Citations number
23
Categorie Soggetti
Material Science
Journal title
Materials research bulletin → ACNP
ISSN journal
00255408
Volume
29
Issue
12
Year of publication
1994
Pages
1307 - 1314
Database
ISI
SICI code
0025-5408(1994)29:12<1307:AWCCP>2.0.ZU;2-E
Abstract
A new calcium copper orthophosphate Ca10Cu(PO4)7 has been prepared and characterized. The compound is stable in the temperature range of 300 -1200 K in inert atmosphere or 300-680 K in air. The compound Ca10Cu(P O4)7 is crystallized in the rhombohedral system with whitlockite-type structure. The space group is R3c, the lattice constants are: a=10.442 (1), c=37.39(1)angstrom, V=3531(1)angstrom3. There are two different c opper sites in the structure.