ELECTRONIC STATES AND RADIATIVE TRANSITIONS IN LIAR

Authors
GU JP HIRSCH G BUENKER RJ PETSALAKIS ID THEODORAKOPOULOS G HUANG MB
Citation
Jp. Gu et al., ELECTRONIC STATES AND RADIATIVE TRANSITIONS IN LIAR, Chemical physics letters, 230(6), 1994, pp. 473-479
Citations number
20
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
230
Issue
6
Year of publication
1994
Pages
473 - 479
Database
ISI
SICI code
0009-2614(1994)230:6<473:ESARTI>2.0.ZU;2-Z
Abstract
Ab initio MRD-CI calculations have been carried out on the ground and the eight lowest excited electronic states of LiAr, correlating with e xcited Li atom states up to 3d D-2. The ground (X (2) Sigma(2s)) and 2 (2) Sigma(+) (2p) electronic states are repulsive while the higher ex cited states show shallow Rydberg minima. Rates of radiative bound-bou nd and bound-free transitions have been also calculated.