HIGH-RESOLUTION INFRARED-ABSORPTION SPECTROSCOPY OF JET-COOLED MOLECULAR-IONS

Citation
M. Fukushima et al., HIGH-RESOLUTION INFRARED-ABSORPTION SPECTROSCOPY OF JET-COOLED MOLECULAR-IONS, Chemical physics letters, 230(6), 1994, pp. 561-566
Citations number
38
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
230
Issue
6
Year of publication
1994
Pages
561 - 566
Database
ISI
SICI code
0009-2614(1994)230:6<561:HISOJM>2.0.ZU;2-I
Abstract
Rovibrational spectra of H-3(+), HN2+, and H3O+ generated in discharge jet-expansion have been studied using a difference-frequency infrared source. The rotational temperatures were determined to be 120 +/- 20, 273 +/- 20 and 150 +/- 20 K for H-3(+), HN2+, and H3O+, respectively. Some dynamic phenomena of the jet-discharges are also discussed.