ATTEMPTS TO PHOTOSTABILIZE PAPER MADE FROM HIGH-YIELD PULP BY APPLICATION OF UV SCREENS CONTAINING GROUPS TO AID THEIR COMPATIBILITY WITH CELLULOSE AND LIGNIN
A. Castellan et al., ATTEMPTS TO PHOTOSTABILIZE PAPER MADE FROM HIGH-YIELD PULP BY APPLICATION OF UV SCREENS CONTAINING GROUPS TO AID THEIR COMPATIBILITY WITH CELLULOSE AND LIGNIN, Journal of photochemistry and photobiology. A, Chemistry, 84(3), 1994, pp. 311-316
2,4-dihydroxybenzophenone (DHB) is known to be a reasonably efficient
UV screen for preventing the colour reversion of papers made from high
-yield pulps. Attempts have been made to improve the performance of th
is material by increasing its compatibility with cellulose and by the
introduction of cationic groups which will help it to locate in lignin
-rich areas. The latter has proved successful and the results show tha
t, on a molar basis for the 2,4-dihydroxybenzophenone nucleus, the eff
iciency is increased by the introduction of ammonium and thiouronium g
roups. An interesting finding was that a 2,4-dialkyloxyderivative of b
enzophenone showed similar protective power to that observed for DHB.