ATTEMPTS TO PHOTOSTABILIZE PAPER MADE FROM HIGH-YIELD PULP BY APPLICATION OF UV SCREENS CONTAINING GROUPS TO AID THEIR COMPATIBILITY WITH CELLULOSE AND LIGNIN

Citation
A. Castellan et al., ATTEMPTS TO PHOTOSTABILIZE PAPER MADE FROM HIGH-YIELD PULP BY APPLICATION OF UV SCREENS CONTAINING GROUPS TO AID THEIR COMPATIBILITY WITH CELLULOSE AND LIGNIN, Journal of photochemistry and photobiology. A, Chemistry, 84(3), 1994, pp. 311-316
Citations number
17
Categorie Soggetti
Chemistry Physical
ISSN journal
10106030
Volume
84
Issue
3
Year of publication
1994
Pages
311 - 316
Database
ISI
SICI code
1010-6030(1994)84:3<311:ATPPMF>2.0.ZU;2-I
Abstract
2,4-dihydroxybenzophenone (DHB) is known to be a reasonably efficient UV screen for preventing the colour reversion of papers made from high -yield pulps. Attempts have been made to improve the performance of th is material by increasing its compatibility with cellulose and by the introduction of cationic groups which will help it to locate in lignin -rich areas. The latter has proved successful and the results show tha t, on a molar basis for the 2,4-dihydroxybenzophenone nucleus, the eff iciency is increased by the introduction of ammonium and thiouronium g roups. An interesting finding was that a 2,4-dialkyloxyderivative of b enzophenone showed similar protective power to that observed for DHB.