EFFICIENT ONE-POT PROCEDURES FOR THE PREPARATION OF SECONDARY PHOSPHINES

Citation
L. Brandsma et al., EFFICIENT ONE-POT PROCEDURES FOR THE PREPARATION OF SECONDARY PHOSPHINES, Synthetic communications, 24(22), 1994, pp. 3219-3223
Citations number
1
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00397911
Volume
24
Issue
22
Year of publication
1994
Pages
3219 - 3223
Database
ISI
SICI code
0039-7911(1994)24:22<3219:EOPFTP>2.0.ZU;2-J
Abstract
Secondary phosphines R(2)PH or RR'PH (R and R' = alkyl, cycloalkyl) ha ve been obtained in good yields by preparing lithium phosphide from li thium, red phosphorus and t-butylalcohol in liquid ammonia and subsequ ent alkylation in the presence of alkali amide, prepared in the same f lask.