We determine the velocity correlation function, pairwise peculiar velo
city difference, and rms pairwise peculiar velocity dispersion of rich
clusters of galaxies, as a function of pair separation, for three cos
mological models: Omega = 1 and Omega = 0.3 cold dark matter (CDM), an
d Omega = 0.3 primeval baryonic isocurvature (PBI) models (all flat an
d COBE-normalized). We find that close cluster pairs, with separation
r less than or equal to 10 h(-1) Mpc, exhibit strong attractive peculi
ar velocities in all models; the cluster pairwise velocities depend se
nsitively on the model. The mean pairwise attractive velocity of clust
ers on 5 h(-1) Mpc scale ranges from similar to 1700 km s(-1) for Omeg
a = 1 CDM to similar to 1000 km s(-1) for PBI to similar to 700 km s(-
1) for Omega = 0.3 CDM. The small-scale pairwise velocities depend als
o on cluster mass: richer, more massive clusters exhibit stronger attr
active velocities than less massive clusters. On large scales, from si
milar to 20 to 200 h(-1) Mpc, the cluster peculiar velocities are incr
easingly dominated by bulk and random motions; they are independent of
cluster mass. The cluster velocity correlation function is negative o
n small scales for Omega = 1 and Omega = 0.3 CDM, indicating strong pa
irwise motion relative to bulk motion on small scales; PBI exhibits re
latively larger bulk motions. The cluster velocity correlation functio
n is positive on very large scales, from r similar to 10 h(-1) Mpc to
r similar to 200 h(-1) Mpc, for all models. These positive correlation
s, which decrease monotonically with scale, indicate significant bulk
motions of clusters up to similar to 200 h(-1) Mpc. The strong depende
nce of the cluster velocity functions on models, especially at small s
eparations, makes them useful tools in constraining cosmological model
s when compared with observations.