CHARACTERIZATION BY PYROLYSIS-GAS CHROMATOGRAPHY MASS-SPECTROMETRY OFTHE ALKALILIGNIN OBTAINED FROM WHEAT-STRAW SODA-COOKING EFFLUENTS AFTER TREATMENT WITH STREPTOMYCES STRAINS
J. Rodriguez et al., CHARACTERIZATION BY PYROLYSIS-GAS CHROMATOGRAPHY MASS-SPECTROMETRY OFTHE ALKALILIGNIN OBTAINED FROM WHEAT-STRAW SODA-COOKING EFFLUENTS AFTER TREATMENT WITH STREPTOMYCES STRAINS, Rapid communications in mass spectrometry, 10(15), 1996, pp. 1869-1872
Alkalilignin samples obtained from untreated paper-mill effluent and e
ffluent decolorized by Streptomyces UAH 30 and Streptomyces UAH 51 wer
e analyzed by pyrolysis/gas chromatography/mass spectrometry, The mole
cular composition of the samples and the chemical modifications occurr
ing in the lignin units were studied in order to know the mechanism of
decolorization carried out by these microorganisms. The pyrolysis dat
a showed a notable reduction in the lignin pyrolysis products of alkal
ilignins in effluent decolorized by Streptomyces strains, Moreover, ch
emical modifications, such as oxidation and shortening of the side cha
in of the phenyl-propyl moieties of lignin were also detected.