A NOVEL LEWIS-ACID-CATALYZED 1,2-OME SHIFT REACTION OF AN ACETYLENIC ETHER ON A DIPALLADIUM FRAMEWORK - X-RAY STRUCTURE OF [PD2CL2(MU-DPPM)(2)(MU-C=C(OME)(ME))]

Authors
KLUWE C MULLER J DAVIES JA
Citation
C. Kluwe et al., A NOVEL LEWIS-ACID-CATALYZED 1,2-OME SHIFT REACTION OF AN ACETYLENIC ETHER ON A DIPALLADIUM FRAMEWORK - X-RAY STRUCTURE OF [PD2CL2(MU-DPPM)(2)(MU-C=C(OME)(ME))], Journal of organometallic chemistry, 526(2), 1996, pp. 385-387
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
526
Issue
2
Year of publication
1996
Pages
385 - 387
Database
ISI
SICI code
0022-328X(1996)526:2<385:ANL1SR>2.0.ZU;2-5
Abstract
Treatment of [Pd2Cl2(mu-dppm)(2)] with MeOC=CMe in CH2Cl2 in the prese nce of catalytic amounts of HBF4 . Et(2)O led to the formation of [Pd2 Cl2(mu-dppm)(2)(mu C=C(OMe)(Me))] via a 1,2-OMe shift reaction. The co mplex was characterized crystallographically.