SELF-INTERSTITIALS AS BASIC STRUCTURAL UNITS OF LIQUIDS AND GLASSES

Authors
Citation
Av. Granato, SELF-INTERSTITIALS AS BASIC STRUCTURAL UNITS OF LIQUIDS AND GLASSES, Journal of physics and chemistry of solids, 55(10), 1994, pp. 931-939
Citations number
36
Categorie Soggetti
Physics, Condensed Matter",Chemistry
ISSN journal
00223697
Volume
55
Issue
10
Year of publication
1994
Pages
931 - 939
Database
ISI
SICI code
0022-3697(1994)55:10<931:SABSUO>2.0.ZU;2-#
Abstract
A recently given interstitialcy model for simple condensed matter stat es is tested by comparing predicitions of the model with available evi dence for (1) the structure as given by the radial distribution functi on, (2) the dynamics of grasses found for the generalized vibrational density of states from inelastic neutron scattering measurements, and thermodynamic properties in the crystalline, glassy and liquid stales given by (3) lattice parameter measurement determination of the therma l equilibrium concentration of interstitials in the crystalline stage, (4) the ratio of Young's modulus to volume changes during relaxation in the glassy state, and (5) the magnitude and temperature dependence of the specific heat in the liquid state. The structure, dynamics and thermodynamic properties are accounted for easily, simply and naturall y in a quantitative, comprehensive and unified way by the interstitalc y model.