Av. Granato, SELF-INTERSTITIALS AS BASIC STRUCTURAL UNITS OF LIQUIDS AND GLASSES, Journal of physics and chemistry of solids, 55(10), 1994, pp. 931-939
A recently given interstitialcy model for simple condensed matter stat
es is tested by comparing predicitions of the model with available evi
dence for (1) the structure as given by the radial distribution functi
on, (2) the dynamics of grasses found for the generalized vibrational
density of states from inelastic neutron scattering measurements, and
thermodynamic properties in the crystalline, glassy and liquid stales
given by (3) lattice parameter measurement determination of the therma
l equilibrium concentration of interstitials in the crystalline stage,
(4) the ratio of Young's modulus to volume changes during relaxation
in the glassy state, and (5) the magnitude and temperature dependence
of the specific heat in the liquid state. The structure, dynamics and
thermodynamic properties are accounted for easily, simply and naturall
y in a quantitative, comprehensive and unified way by the interstitalc
y model.