HOMOLOGATION OF REPRESENTATIVE BORONIC ESTERS USING IN-SITU GENERATED(HALOMETHYL)LITHIUMS - A COMPARATIVE-STUDY

Authors
SOUNDARARAJAN R LI GS BROWN HC
Citation
R. Soundararajan et al., HOMOLOGATION OF REPRESENTATIVE BORONIC ESTERS USING IN-SITU GENERATED(HALOMETHYL)LITHIUMS - A COMPARATIVE-STUDY, Tetrahedron letters, 35(48), 1994, pp. 8957-8960
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
48
Year of publication
1994
Pages
8957 - 8960
Database
ISI
SICI code
0040-4039(1994)35:48<8957:HORBEU>2.0.ZU;2-0
Abstract
A comparative study of the homologation of representative boronic este rs with in situ generated LiCH(2)X (X = Cl; Br; I) is presented wherei n the reactivity differences arising out of the steric and electronic effects of the migrating groups, and the nature of the ester groups ar e determined and discussed.